Bowls, Vases and Goblets – The Microcrockery of Polymer and Nanocomposite Morphology Revealed by Optical Tomography
Yang Shugui (1), Wei Zhen-Zhen (2), Cseh Liliana (3), Kazemi Pantea (4), Zeng Xiang-bing (5), Xie Hui-Jie (6), Saba Hina (6), Ungar Goran (1)*
(1) Xi’an Jiaotong University - Shaanxi - China, (2) Soochow University - Jiangsu - China, (3) Coriolan Dragulescu Institute of Chemistry - Timisoara - Romania, (4) University of Sheffield - Sheffield - UnitedKingdom, (5) University of Sheffield - Sheffield - UnitedKingdom, (6) Zhejiang Sci-Tech University - Zhejiang - China
On the >1µm scale the morphology of semicrystalline plastics features spherulites, “shish-kebabs”, cylinddrites and other crystalline aggregates which strongly affect mechanical and other material properties. Current imaging techniques give only a 2D picture of these objects. Here we show how they can be visualized in 3D using fluorescent labels and two-photon confocal microscopy. As a result, for the first time we see spherulites in 3D, both in neat polymers and in their nanocomposites, and observe how unevenly nanoparticles and other additives are distributed in the material. Images of i-polypropylene and poly(lactic acid) reveal previously unsuspected morphologies such as “vases” and “goblets”, nonspherical “spherulites” and, unexpectedly, “shish-kebabs” grown from static melt. Also surprisingly, in nanocomposite sheets spherulite nucleation is seen to be copied from one surface to another, mediated by crystallization-induced pressure drop and local melt-flow. These first results reveal unfamiliar modes of self-assembly in familiar plastics and open new perspectives on polymer microstructure.