POLYETHYLENE-CELLULOSE COMPOSITES AND NANOCOMPOSITES. I. Effect of FIBER SIZE AND COMPOSITION
Maia Thiago Henrique Silveira (1), Calazans Marília (1), Lima Vitor (1), Moreira Francys Kley Vieira (1), Lucas Alessandra de Almeida (1)*
(1) University Federal of São Carlos - São Paulo - Brazil
The use of cellulose nanofibrils (CNF), conventional bleached micrometric cellulose pulp fibers (CF) and lignocellulose nanofibrils (LCNF) has been explored in a polyolefin aqueous dispersion based on ethylene copolymer modified with 6 wt.% of acrylic acid. The addition of 5, 10 and 30 wt% of fibers to neat PE act as reinforcement and increase the Young’s modulus. The PE/LCNF composite exhibit a two-fold increase on Young’s modulus of nanocomposite films containing 10 and 30 wt.%. The PE/CNF and PE/CF films are transparent to naked eye up to 10 wt%, while PE/LCNF are yellowish. The resultant composites showed high thermal stability on processing and application temperatures with only a slight reduction in the thermal degradation temperatures compared to the neat PE and a very low degree of water absorption.