pps proceeding
Symposium: S07 - Fibers and Films Poster Presentation
Transfer-Printing of Self-folding polymer-metal bilayer film
Thomas Patrick (1)*, de Leon Al Christopher C (1), Barnes Andrew (2), O`Donnell Jonathan (1), Zorman Christian (2), Advincula Rigoberto C. (1)
(1) Department of Macromolecular Science and Engineering, Case Western Reserve University - Ohio - USA, (2) Department of Electrical Engineering and Computer Science, Case Western Reserve University - Ohio - USA
We introduced a simple and robust alternative for fabricating stimuli-responsive 2D self-folding film. The approach combines metal-sputtering, layer-by-layer assembly of polyelectrolytes, and transfer-printing of the bilayer film onto a substrate coated with a sacrificial layer. With this technique, self-folding bilayer films can be fabricated without using harsh chemical etchants, complicated chemical synthesis, or complex lithographic techniques. Upon release, the micro-sized 2D film is shown to reconfigure into a 3D-structure caused by a mismatch in the properties of the individual layers. The actuation of the bilayer film can be triggered by partial swelling due to absorption of water or by partial expansion due to an increase in temperature of one of the layers.